Yerofieiev A.M., Ishkov V.V., Kozii Ye.S., Bartashevskiy S.Ye. Geochemical features of nickel in the oils of the Dnipro-Donetsk basin

Details

Parent Category: Geo-Technical Mechanics, 2022

Category: Geo-Technical Mechanics, 2022, № 160

Geoteh. meh. 2022, 160, 5-16

https://doi.org/10.15407/geotm2022.160.005

 

GEOCHEMICAL FEATURES OF NICKEL IN THE OILS OF THE DNIPRO-DONETSK BASIN

¹Yerofieiev A.M., ²Ishkov V.V., ³Kozii Ye.S., ³Bartashevskiy S.Ye.

¹V. N. Karazin Kharkiv National University, ²Institute of Geotechnical Mechanics named by N. Poljakov of National Academy of Sciences of Ukraine, ³National Technical University “Dnipro Polytechnic”

UDC 550.423

Language: English

Abstract. The results of long-term research of geochemical features of nickel in oils from 36 deposits of the main oil and gas region of Ukraine - the Dnipro-Donetsk basin are presented: Bakhmachske, Prylukske, Krasnozayarske, Kachalivske, Kremenivske, Karaykozovske, Korobochkynske, Kulychykhinske, Lipovodolynske, Monastyryshchenske, Matlakhivske, Malosorochynske, Novo-Mykolayivske, Perekopivske, Prokopenkivske, Radchenkovske, Raspashnovske, Sofiivske, Sukhodolivske, Solontsivske, Solokhivske, Talalaivske, Trostyanets'ke, Turutynske, Zakhidno-Kharkivtsivske, Shchurynske, Yuryivske, Yaroshivske, Khukhryanske, Sagaidatske №1, Sagaidatsk №13, Kybytsivske №5, Kybytsivske №51, Kybytsivske №52, Kybytsivske №56, Kybytsivske №1. The results of correlation and regression analyzes revealed the character and forms of the relationship between the nickel content in oils and vanadium; zinc; chromium; the total content of V, Zn, Cr, Mn, Co, Fe, Hg, Al; average thickness of the productive horizon; oil density values; oil viscosity values; resin content; formation water density from the productive horizon; sulfur content in oil; manganese; cobalt; metal; mercury; aluminum; the current depth of the productive horizon; modern temperature of the productive horizon; modern pressure in the productive horizon; oil initial boiling point temperature; the content of paraffins; salinity values of formation water from the productive horizon; content of asphaltenes. The calculated correlation coefficients, linear pair regression equations and their graphs between these parameters are given. Based on the results of cluster analysis, a dendrogram of the results of clustering by the weighted centroid method of deposits on the nickel content in the oils of the considered deposits was constructed. Considering the statistically significant character of nickel connections, it is proposed to divide all geochemical and geological-technological parameters into a group of genetically and / or paragenetically related to the accumulation of nickel in oil and a group of negatively associated with increasing nickel in oil. Based on the results of clustering by the weighted centroid method, the first natural classification of deposits by nickel content in oils was developed. It has been proved that asphaltenes are the main nickel concentrators in the oil of the studied deposits. It is shown that according to the results of cluster analysis, the sample averages of nickel concentrations that differ significantly between individual deposits or groups of deposits in the established series can be interpreted in the terminology of qualitative assessment as: abnormally low; low; below average; medium; above average; high; abnormally high. The implementation of this approach makes it possible to visually compare and interpret in geological terms experimentally obtained all different-scale and diverse indicators of oil deposits.
Keywords: nickel, oil deposits, cluster analysis, linear regression equations, geochemical parameters of oil, correlation coefficient.

 

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About the authors:

Yerofieiev Artem Mykolaiovych, Postgraduate Student, V. N. Karazin Kharkiv National University, Kharkiv, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.

Ishkov Valerii Valeriiovych, Candidate of Geological and Mineralogical Sciences (Ph.D.), Senior Research Fellow of Laboratory of Studies of Structural Changes Rocks, Institute of Geotechnical Mechanics named by N. Poljakov of National Academy of Sciences of Ukraine (IGTM NAS of Ukraine), Dnipro, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.

Kozii Yevhen Serhiiovych, Candidate of Geological Sciences (Ph.D.), Deputy Director of Educational and Scientific Center for Training of Foreign Citizens, National Technical University “Dnipro Polytechnic” (NTU "DP"), Dnipro, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.

Bartashevskiy Stanislav Yevhenovych, Candidate of Technical Sciences (Ph.D.), Associate Professor, Head of the Department of Transport Systems and Technologies, National Technical University “Dnipro Polytechnic” (NTU "DP"), Dnipro, Ukraine, bartashevskyi. This email address is being protected from spambots. You need JavaScript enabled to view it.

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