Serhii Zybailo, Viktor Ved, Denis Shapovalov. Features of process of epoxidation of natural rubber scrap in water-xylene
- Details
- Parent Category: Geo-Technical Mechanics, 2020
- Category: Geo-Technical Mechanics, 2020, Issue 155
Geoteh. meh. 2020, 155, 197-201
https://doi.org/10.1051/e3sconf/202016800039
FEATURES OF PROCESS OF EPOXIDATION OF NATURAL RUBBER SCRAP IN WATER-XYLENE
1Serhii Zybailo, 1Viktor Ved, 1Denis Shapovalov
1Ukrainian State University of Chemical Technology
Language: English
Abstract. The article presents the analysis of the existing methods of producing epoxidized polydiene rubbers in order to obtain new derivative materials with improved physical and mechanical properties. The study proves the use of natural rubber as a raw material for the production of epoxidized polydiene. It has been experimentally demonstrated that conducting epoxidation as a combined-separation process allows producing epoxidized rubber in one reaction volume. It has been also found that the use of a water-xylene environment for the process has a qualitative effect on the degree of epoxidation and significantly reduces power consumption.
REFERENCES
1. Dyrda, V. Kobets, A. Bulat, I. Lapin, V. Lysytsia, N. Ahaltsov, H., Sokol, S. Vibroseismic protection of heavy mining machines, buildings and structures. E3S Web of Conferences, International Conference Essays of Mining Science and Practice, 109 (2019). https://doi.org/10.1051/e3sconf/201910900022
2. Bulat, A. Voloshyn, O., Zhevzhik, O. (2013). Plasma reactor for thermochemical preparation of coal-air mixture before its burning in the furnaces. Annual Scientific-Technical Colletion - Mining of Mineral Deposits 2013. 39-44. https://doi.org/10.1201/b16354-8
3. Abdullin, M.I., Glazyrin, A.B., Kukovinets, A.S., Basyrov, A.A., Valekzhanin, I.V., Klisova, G.U. (2012) Sposob polucheniia epoksidirovannykh 1,2-polibutadienov. Patent № 2465285, Russia
4. Abdullin, M.I., Glazyrin, A.B., Kukovinets, A.S., Basyrov, A.A., Valekzhanin, I.V., Klisova, G.U. (2013) Sposob polucheniia epoksidirovannykh 1,2-polibutadienov. Patent № 2486207, Russia
5. Shapovalov, D.O., Ved, V.V., Zybailo, S.M., Yushko, V.L. (2014). Epoxidation of natural rubber in water-xylene environment. Voprosy khimii i khimicheskoi tekhnologii, (3), 102-106. https://doi.org/10.6084/ m9.figshare.12084069
6. Kwo, K.H. (2007). Study of adhesion properties of natural rubber, epoxidized natural rubber, and ethylene-propylene dieneterpolymer-based adhesives. Universiti Sains Malaysia (USM). Penang, Malaysia
7. Fituni, Yu.A., Trachevskyi, V.V. (2011). Investigation of modifications of natural rubber with ethylene glycol. Vostochno-Evropeyskiy zhurnal peredovykh tekhnologiy [Eastern-European Journal of Enterprise Technologies], 3 (6), 44-47
8. Akhmedianova, R.A., Miloslavskii, D.G., Kharlampidi, K.E., Dak, V.M., Tkhai, N.T., Liem, N.T. (2015). Epoxidation of styrene-butadiene and natural rubber in the form of latex with hydrogen peroxide in the presence of a peroxophosphate-tungstate catalyst system. Promyshlennoe proizvodstvo i ispolzovanie elastomerov, (4), 3-6
9. Osamu, H. Hideo, K. Yukio, M. (1985) Process for producing hydrophilic polymers. Patent № US4528340A, USA
10. Shapovalov, D.O., Zybailo, S.M., Yushko, V.L. (2017) Sposib otrymannia epoksydovanykh polidiieniv. Patent № 118007, Ukraine
11. Zybaylo, S. Ved, V. Okhtina, O. Kiselev, V. Shapovalov, D. (2019). Optimization of the process of obtaining epoxidized natural rubber for the development of new composite materials on its basis. Technology audit and production reserves, 6, 3(50), 10-15. https://doi.org/10.15587/2312-8372.2019.184364
12. Shapovalov, D.O. Zybailo, S.M. Yushko, V.L. (2014). Combined reaction and separation process for the epoxidation of natural rubber waste. Sovremennye innovatsionnye tekhnologii podgotovki inzhenernykh kadrov dlia gornoi promyshlennosti i transporta. 324-327.
13. Shapovalov, D.O. Zybailo, S.M. Ved, V.V. (2016). Studies on the kinetics of epoxidation of natural rubber scrap. Sovremennye innovatsionnye tekhnologii podgotovki inzhenernykh kadrov dlia gornoi promyshlennosti i transporta. 220-225.