GROUNDWATER HALOGENS IN THE OIL- AND GAS-CONTAINED REGIONS OF THE DNIEPER- DONETS DEPRESSION

UDC 550.84

Authors:

N.O. Kryuchenko, D.Sc. (Geol.),Senior Researcher,

E.Ya. Zhovinsky, Cor. Member NASU,

D.Sc. (Geol.-Min.), Professor,

M.V. Kuhar, M.S. (Tech.),

K.E. Dmytrenko, M.S. (Tech.)

(IGMP OF NASU)

Abstract.Purpose of this study was to determine geochemical regularities of changes in chemical composition of oil- and gas-contained waters in the Dnieper-Donets depression and to explain specific distribution of halogens in the waters. To study the water chemical composition, methods of chemical and potentiometric analysis, and atomic absorption were used; the findings were interpreted with the help of basic programs of statistical analysis. The findings show that oil water and gas-condensate water from the Talalaivk Rybalsk field and Glinsk Solohovsk field in the gas- and oil-contained regions are highly salt (mineralization is above 150 g/dm3). In the northwestern part of the territory (Velikobubnovsk and Talalaivk deposits), waters show high average content of chlorine and bromine (160 g/dm3 and 0,18 g/dm3, respectively), and in the southeastern part (Opishnyansk deposit) − high average iodine content (0,018 g/dm3); such high contents exceeding 2−3 times figures for other fields can be explained by presence of tectonic disturbances. Since the waters from all oil and gas deposits feature direct correlation between salinity and chlorine, bromine and iodine content it can be concluded that it is reasonable to take into account a halogen component in order to identify any oil- and gas-contained areas. Further study of the regularities of halogens distribution in groundwater of the oil and gas fields will improve hydrogeochemical methods for searching the gas- and oil field.

Keywords: halogens, oil water, oil and gas field

References:

1. Bielecki, V. (ed) (2004), Encyclopedic Dictionary of Mining, v.3, West Publishing House, Donetsk, Ukraine.

2. Lukin, A.E , (2010), “Artificial hydrocarbon deposits and geological background of their creation in the oil and gas regions of Ukraine” Geological journal, vol. 1, pp. 42-57.

3. Tovar & Information Services (2007) “Oil as a commodity” available at: http://www.znaytovar.ru/s/Neft-kak-tovar.html (Accessed 3 November 2013).

4. Tovar & Information Services (2007) “OST 51.58-79 gas condensates. Technological classification” available at: http://www.znaytovar.ru/gost/2/OST_515879_Kondensaty_gazovye.html  (Accessed 5 November 2013).

About the authors:

Kryuchenko Nataliya Olegovna,Doctor of Geology (D.Sc.), Senior Researcher, Senior Researcher in Department of Exploration andEnvironmental Geochemistry, M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation under the National Academy of Science of Ukraine (IGMOF, NASU), Kiev, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.

Zhovinsky Eduard Yakovlevich,Corresponding Member of the National Academy of Science of Ukraine, Doctor of Geology and Mineralogy (D.Sc.), Professor, Head of Department of Exploration and Environmental Geochemistry, M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation under the National Academy of Science of Ukraine (IGMOF, NASU), Kiev, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.

Kuhar Mikhail Vladimirovich,Junior Researcher in Department of Exploration andEnvironmental Geochemistry, M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation under the National Academy of Science of Ukraine (IGMOF, NASU), Kiev, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.

DmytrenkoK.E., Junior Researcher in Department of Exploration andEnvironmental Geochemistry, M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation under the National Academy of Science of Ukraine (IGMOF, NASU), Kiev, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.

 

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