Kholiavchenko L.Т., Pigida E.Yu., Demchenko S.V., Davydov S.L. Chemical kinetics of process of disperse carbon-containing media recycling in water-steam plasma

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Parent Category: Geo-Technical Mechanics, 2016

Category: Geo-Technical Mechanics, 2016, Issue 129

Geoteh. meh. 2016, 129, 181-189

CHEMICAL KINETICS OF PROCESS OF DISPERSE CARBON-CONTAINING MEDIA RECYCLING IN WATER-STEAM PLASMA

¹Kholiavchenko L.Т., ¹Pigida E.Yu., ¹Demchenko S.V., ¹Davydov S.L.

¹IGTM NAS of Ukraine

Abstract.Chemical kinetics of thermal conversion process of carbon-containing media at high temperature (2000 K ≤T ≤5000 K) processing in the chamber of the reactor using a plasma jet as the oxidant vapor was studied. Rate of chemical reactions was calculated by procedure set out for defining kinetic constants of the process of coal-water fuel gassing. Impact of gaseous medium temperature in the chamber on the time of full conversion of fuel carbon particles was specified. As an example, parameters of process of coke particle (size (5 ÷ 20) ∙ 10-5 m) gasification are calculated with coefficient of excess oxidant α = 0,45 and fuel consumption mT = 100kg / h. Expediency of the steam-plasma gasification process at temperature of gas in the reactor chamber up to 3000 K is grounded.

Keywords: chemical kinetics, vapor-plasma processing, hydrocarbon fuel, carbon-containing media, gasification process.

REFERENCES

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About the authors:

Kholiavchenko Leonid Тimofeevich, Candidate of Technical Sciences (Ph.D.), Senior Researcher in Department of Rock Breaking Problems, M.S. Polyakov Institute of Geotechnical Mechanics under the National Academy of Sciences of Ukraine (IGTM, NASU), Dnepr, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. .

Pigida Evgeniy Yuryevich, Candidate of Technical Sciences (Ph.D.), Senior Researcher in Department of Rock Breaking Problems, M.S. Polyakov Institute of Geotechnical Mechanics under the National Academy of Sciences of Ukraine (IGTM, NASU), Dnepr, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. .

Demchenko Sergey Vyacheslavovich, Master of Science, Junior Researcher in Department of Rock Breaking Problems, M.S. Polyakov Institute of Geotechnical Mechanics under the National Academy of Sciences of Ukraine (IGTM, NASU), Dnepr, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. .

Davydov Sergey Leonidovich, Master of Science, Junior Researcher in Department of Rock Breaking Problems, M.S. Polyakov Institute of Geotechnical Mechanics under the National Academy of Sciences of Ukraine (IGTM, NASU), Dnepr, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. .

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